Contamination of Caribbean coastal waters by the antifouling herbicide Irgarol 1051

Irgarol 1051 is a s-triazine herbicide used in popular slime-resistant antifouling paints. It has been shown to be acutely toxic to corals, mangroves and sea grasses, inhibiting photosynthesis at low concentrations (>50 ng l(-1)). We present the first data describing the occurrence of Irgarol 1051 in coastal waters of the Northeastern Caribbean (Puerto Rico (PR) and the US Virgin Islands (USVI)). Low level contamination of coastal waters by Irgarol 1051 is reported, the herbicide being present in 85% of the 31 sites sampled. It was not detected in water from two oceanic reference sites. In general, Irgarol 1051was present at concentrations below 100 ng l(-1), although far higher concentrations were reported at three locations within Benner Bay, USVI (223-1,300 ng l(-1)). The known toxicity of Irgarol 1051 to corals and sea grasses and our findings of significant contamination of the Northeastern Caribbean marine environment by this herbicide underscore the importance of understanding, more fully, local and regional exposure of reef and sea grass habitats to Irgarol 1051 and, where necessary, implementing actions to ensure adequate protection of these important ecosystems.     

The Apparent Layered Structure of the Heliospheric Current Sheet: Multi-Spacecraft Observations

Solar Physics - Multiple current sheet crossings are ubiquitous features of the solar wind associated with high-beta plasma sheets, notably during the passage of the heliospheric current sheet...     

Quaternary glaciation in the Nubra and Shyok valley confluence, northernmost Ladakh, India

Three glacial stages (Deshkit 1, Deshkit 2 and Dishkit 3 glacial stages) are identified in the Nubra and Shyok valleys in northernmost Ladakh, northwest India, on the basis of geomorphic field mapping, remote sensing, and ¹⁰Be terrestrial cosmogenic nuclide surface exposure dating. The glacial stages date to ∼ 45 ka (Deshkit 1 glacial stage), ∼ 81 ka (Deshkit 2 glacial stage) and ∼ 144 ka (Deshkit 3 glacial stage). A mean equilibrium line altitude depression of ∼ 290 m for the Deshkit 1 glacial stage was calculated using the area accumulation ratio, toe-to-headwall ratio, area-altitude, and area-altitude balance ratio methods. Comparison of glaciation in the Nubra and Shyok valleys with glaciations in the adjacent Central Karakoram of northern Pakistan and northern side of the Ladakh Range of northern India indicates that glaciation was synchronous on Milankovitch timescales across the region during MIS-6, but differed greatly in extent, with more extensive glaciation in the Karakoram than the morphostratigraphically equivalent glaciation on the northern slopes of the Ladakh Range. This highlights the strong contrast in the extent of glaciation across ranges in the Himalaya-Tibetan orogen, necessitating caution when correlating glacial successions within and between mountain ranges.     

Meridian-scanning photometer, coherent HF radar, and magnetometer observations of the cusp: a case study

The dynamics of the cusp region and post-noon sector for an interval of predominantly IMF B_y, B_z < 0 nT are studied with the CUTLASS Finland coherent HF radar, a meridian-scanning photometer located at Ny Ålesund, Svalbard, and a meridional network of magnetometers. The scanning mode of the radar is such that one beam is sampled every 14 s, and a 30° azimuthal sweep is completed every 2 minutes, all at 15 km range resolution. Both the radar backscatter and red line (630 nm) optical observations are closely co-located, especially at their equatorward boundary. The optical and radar aurora reveal three different behaviours which can interchange on the scale of minutes, and which are believed to be related to the dynamic nature of energy and momentum transfer from the solar wind to the magnetosphere through transient dayside reconnection. Two interpretations of the observations are presented, based upon the assumed location of the open/closed field line boundary (OCFLB). In the first, the OCFLB is co-located with equatorward boundary of the optical and radar aurora, placing most of the observations on open field lines. In the second, the observed aurora are interpreted as the ionospheric footprint of the region 1 current system, and the OCFLB is placed near the poleward edge of the radar backscatter and visible aurora; in this interpretation, most of the observations are placed on closed field lines, though transient brightenings of the optical aurora occur on open field lines. The observations reveal several transient features, including poleward and equatorward steps in the observed boundaries, braiding of the backscatter power, and 2 minute quasi-periodic enhancements of the plasma drift and optical intensity, predominantly on closed field lines.     

Recrystallization of quartzofeldspathic rocks in a paleozoic thrust belt, Grand Lake, Newfoundland: Implications for garnet-biotite thermometry

Migmatitic granitic gneiss and associated garnetiferous granite at Grand Lake are tectonically interleaved with high-pressure ( 9 kbar) metapelites that contain Barrovian (Ky-St-Grt-Bt-Ms-Rt) mineral assemblages. The migmatites contain metabasites that are compositionally similar to the latest Proterozoic Long Range dykes, suggesting that the gneisses correlate to Grenvillian inliers in western Newfoundland.

In the metapelites, the Barrovian porphyroblastic assemblage overprints microfolds and is itself overprinted by greenschist-facies assemblages in thrust-related high-strain zones. Evidence that the quartzofeldspathic rocks also experienced Barrovian metamorphism is provided by low Ti/>Al amphiboles in metabasites in the gneiss, and, despite the migmatitic character of these rocks, the presence of growth-zoned garnets with bell-shaped compositional profiles (e.g., rimward increase in X_Prp and decrease in X_Sps) similar to those exhibited by garnet in the metapelite. The range of garnet-biotite paleotemperatures for the quartzofeldspathic rocks is only marginally higher (T_max=530–660°C) than that determined for the metapelites (T_max=500–615°C). There are no systematic differences in Grt-Bt temperatures between (proto) mylonitic rocks and nearby precursors.

These results indicate that the quartzofeldspathic rocks and metapelites share a common, post-migmatization (of the gneisses) metamorphic history; they may well have originally been linked by a basement/cover relationship. Mineralogical evidence for the earlier, higher grade metamorphic history of the migmatites has virtually been eradicated even outside the high-strain zones. In this area, there is no clear relation between qualitatively-estimated superimposed strain and the degree of resetting of the Grt-Bt geothermometer.     

Geographical Dimensions of Environmental Restructuring in New Zealand*

During the 1980s, New Zealand underwent a period of dramatic economic, social, and administrative restructuring. The reform extended to the administrative arrangements for environmental management. A geographic restructuring model is used in this paper to establish the context in which the reforms were carried out. A combination of economic, environmental, and social influences operating at different geographic scales can be identified. These influences are subsequently illustrated through reference to three aspects of the restructuring that have distinct geographical dimensions: the definition of human-environment relations, the spatial definition of planning regions, and the implications of spatial differentiation for resource management policy and practice.     

Role of molecular oxygen in the dissolution of siderite and rhodochrosite

The dissolution of siderite (FeCO₃) and rhodochrosite (MnCO₃) under oxic and anoxic conditions is investigated at 298 K. The anoxic dissolution rate of siderite is 10^−8.65 mol m⁻² s⁻¹ for 5.5 < pH < 12 and increases as [H⁺]^0.75 for pH < 5.5. The pH dependence is consistent with parallel proton-promoted and water hydrolysis dissolution pathways. Atomic force microscopy (AFM) reveals a change in pit morphology from rhombohedral pits for pH > 4 to pits elongated at one vertex for pH < 4. Under oxic conditions the dissolution rate decreases to below the detection limit of 10⁻¹⁰ mol m⁻² s⁻¹ for 6.0 < pH < 10.3, and hillock precipitation preferential to steps is observed in concurrent AFM micrographs. X-ray photoelectron spectroscopy (XPS) and thermodynamic analysis identify the precipitate as ferrihydrite. At pH > 10.3, the oxic dissolution rate is as high as 10^−7.5 mol m⁻² s⁻¹, which is greater than under the corresponding anoxic conditions. A fast electron transfer reaction between solution O₂ or [Fe³⁺(OH)₄]⁻ species and surficial >Fe^II hydroxyl groups is hypothesized to explain the dissolution kinetics. AFM micrographs do not show precipitation under these conditions. Anoxic dissolution of rhodochrosite is physically observed as rhombohedral pit expansion for 3.7 < pH < 10.3 and is chemically explained by parallel proton- and water-promoted pathways. The dissolution rate law is 10^−4.93[H⁺] + 10^−8.45 mol m⁻² s⁻¹. For 5.8 < pH < 7.7 under oxic conditions, the AFM micrographs show a tabular precipitate growing by preferential expansion along the a-axis, though the macroscopic dissolution rate is apparently unaffected. For pH > 7.7 under oxic conditions, the dissolution rate decreases from 10^−8.45 to 10^−9.0 mol m⁻² s⁻¹. Flattened hillock precipitates grow across the entire surface without apparent morphological influence by the underlying rhodochrosite surface. XPS spectra and thermodynamic calculations implicate the precipitate as bixbyite for 5.8 < pH < 7.7 and MnOOH (possibly feitnkechtite) for pH >7.7.     

藏西南纳木那尼峰地区第四纪以来的冰川演化

藏西南纳木那尼峰地区第四纪以来经历了多阶段的冰川演化,遗留了各个阶段不同类型的冰川堆积地貌和冰川侵蚀地貌。文章通过对各阶段冰积地貌的分布范围、特征的描述,并根据保存程度确定其相对地貌年龄,初步认为本地区第四纪以来倒数第3次冰期发育了规模最大的冰原冰川,倒数第2次冰期时冰原缩小并逐渐解体,末次冰期以来完全解体为山谷冰川。根据本地区槽谷的形态特征及冰川堆积物的分布,认为本地区末次间冰期前后有一次活跃的构造运动。     

Inception and demise of a Neoproterozoic ocean basin: evidence from the Ougda complex,western Hoggar (Algeria)

The Neoproterozoic Ougda magmatic complex occurs within platformal carbonate rocks in the western part of the Pan-African fold belt of the Tuareg shield (NW Africa). It is composed of - 800 Ma old, relatively high P-T (i.e., Grt + Cpx-bearing: P > 5 kbar; T≈900'Q, tholeiitic mafic/ultramafic cumulates and related rocks intruded by intermediate to mafic calcalkali plutons (e.g., Cpx+Hbl-bearing gabbro) and dikes. Apparent contrasts in structural level of crystallization indicate that the calc-alkali rocks are significantly younger than the tholeiites, which temporally correlate with a period of regional extension in this part of Africa. Intrusion of the calc-alkali rocks may have occurred during the formation of an arc after the tholeiitic rocks had been (diapirically?) emplaced within the shelf carbonates, and prior to (> 630 Ma) the Pan-African orogeny. Data reported herein indicate that the Ougda complex records the inception and demise of a Neoproterozoic ocean basin. Similar crustal sections have been described from collisional (e.g., Aleutian islands) and extensional (e.g., Ivreä-Verbano zone) settings, indicating that processes operating in both environments can generate nearly indistinguishable igneous suites; the prevalence of shallow-level calc-alkali rocks in both settings may mask the presence of more mafic, tholeiitic rocks at depth.